First, the transmission probability for an electron tunneling through a single rectangular barrier is calculated by the continuous condition of the wave function, then the transmission probability for an electron transverses through a double-barrier structure is also obtained by means of transfer matrix. 利用电子波函数的连接条件,先计算出电子通过一简单方势垒的隧穿几率,再利用转移矩阵方法得到电子通过双势垒的隧穿几率。
Trapping experiment with styrene decreased the amount of S but had no effect on the formation of 4. The reducing property of 1 is discussed and single electron transfer mechanism for the reaction of 1 With 2 is proposed. 用苯乙烯进行捕获实验只减少3的量而对4无影响。根据实验结果对1的还原性进行了讨论,提出1向2发生单电子转移的反应机理。
Single Electron Transfer ( SET) reaction is a rising front field. 有机化合物的单电子转移反应(SET)是一个新兴的前沿领域。
Mechanism of the single electron transfer between clo_2 and phenol 二氧化氯与苯酚的单电子转移反应机理
In this work, we calculated the tunneling probability of a single electron tunneling in a series of asymmetric barriers using the transfer matrix technique in the framework of effective mass approximation. 在有效质量近似的框架下,应用传递矩阵理论研究了势垒的非对称性对单电子隧穿几率的影响。
Single electron transfer and nitration reaction 单电子转移和硝化反应
Thus, photostimulated single electron transfer in CTC followed by expelling chloride ion leads to a biradical, which couples intramolecularly. 所以,光诱导的单电子转移和随后的氯离子离去导致双游离基,双游离基分子内偶合成环。
A non-chain radical anion mechanism induced by single electron transfer from zinc is proposed. 反应可能经锌单电子转移诱发的非链式自由基亲核取代机理。
Evidence for Single Electron Transfer Mechanism in the Hydrolysis of Nitrobenzoic Esters ESR and Spin-trapping Studies 硝基苯甲酸酯水解反应单电子转移机理的证据&ESR和自旋捕获的研究
Calculation of the electronic transmission coefficient for single electron transfer reaction in the coordination compound 配合物单电子转移反应的电子传递系数计算